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Article

Structure and Physicochemical Properties of Water Treated under Nitrogen with Low-Temperature Glow Plasma

1
Institute of Chemistry and Inorganic Technology, Krakow University of Technology, Warszawska Str. 24, 31 155 Krakow, Poland
2
Institute of Chemistry, Jan Dlugosz University, Armii Krajowej Ave. 13-15, 42 201 Częstochowa, Poland
3
Faculty of Food Technology, University of Agriculture in Krakow, Balicka Str. 122, 30 149 Krakow, Poland
4
Nantes Nanotechnological Systems, Dolnych Młynów Str. 24, 59 700 Bolesławiec, Poland
*
Author to whom correspondence should be addressed.
Water 2020, 12(5), 1314; https://doi.org/10.3390/w12051314
Submission received: 23 March 2020 / Revised: 22 April 2020 / Accepted: 1 May 2020 / Published: 7 May 2020
(This article belongs to the Section Water, Agriculture and Aquaculture)

Abstract

:
Water treated with low-temperature, low-pressure glow plasma (GP) in contact with air stimulates various microorganisms, the growth of various plants and provides healthy breeding of various animals. In this paper, we present water treated with GP under oxygen-free nitrogen. It is potentially suitable for breeding anaerobic microorganisms, and increasing the crops of plants utilizing atmospheric nitrogen. Deionized water saturated with oxygen-free nitrogen was treated for 5 to 90 min with low-temperature glow plasma (GP). That operation produced nitrogen in various exited states depending on the treatment time. These excited nitrogen molecules built aqueous clathrates around them. The number and structure of those clathrates depended on the time of the treatment with GP. In terms of mass, density, pH, conductivity, surface tension, Ultraviolet-Visible (UV-VIS), Fourier Transformation Infrared (FTIR), Raman and Electron Spin Resonance (ESR) spectra as well as Differential Scanning Calorimetry (DSC), the macrostructure of water saturated with nitrogen treated with GP strongly depended on the treatment time. Based on the entropy criterion, the macrostructure formed on 30 and 5 min treatment was the most and least organized, respectively.

1. Introduction

In a macrosystem, water molecules form a hydrogen-bonded network with localized and structured clusters. They can arrange into different structures of water, e.g., small ones of four molecules, which may then group into relatively stable octamers. The water molecules also develop much larger water clusters capable of interlinking and translating throughout space. Such clusters dynamically form both open low density and condensed network [1]. The clusters of water can interconvert between lower and higher structures. The presence of dissolved gases and other solutes and temperature affect the equilibrium between these structures influencing the properties of water [2].
There are several methods of physical and physicochemical modifications of the water macrostructure [3]. Among them, modifications with plasma are listed. They involve plasma generated with a variety of methods and various modes of their application. Thus, an abundant number of papers [4,5,6,7,8,9,10,11,12,13,14,15,16,17] describe procedures in which plasma was generated by electric static or pulsed either dc low-voltage or RF discharges inside gas bubbles formed in water. Such treatment produced ozone [8] and hydrogen peroxide [11,13,18,19]. It could also evoke reactions of various organic compounds [20,21]. Oxidative properties of plasma treated water vapor was used for the oxidation of thin titanium films [22]. Since plasma treated water appeared a superior electrolyte, it was applied as anodizing electrolyte for production of nanoporous TiO2 nanotubes [23].
In our recent paper [24] structure and physicochemical properties of water treated with low-temperature, low-pressure glow plasma (GP) in the air was presented. Under fixed parameters of the GP generation, the structure and physicochemical properties of resulting water depended on the time of the GP treatment. It should be mentioned that there is an abundant literature on low-temperature glow plasma. In contrast to corresponding sources (see [25,26,27] and references therein) referring to atmospheric pressure cold plasma, low-pressure plasma was used in our studies.
On such treatment, macrostructure of water was declusterized and, simultaneously, molecules of triplet oxygen dissolved in the water were excited into the singlet state. The latter molecules were stabilized by declusterized water molecules which built aqueous clathrates with the singlet oxygen molecules inside. GP applied in our recent [24] and present studies was distinctly distinguished from plasmas mentioned above. In contrast to other types of plasma, GP generated neither ozone nor hydrogen peroxide and it could not evoke any oxidation of aldehydes or alcohols.
Benefits resulting from the use of that water were shown in a series of subsequent papers. Thus, it was demonstrated that water stimulated growth and pathogenicity of entomopathogenic fungi used as biopesticides [28]. Murawski et al. described benefits of cryopreservation of ram [29] and boar [30] semen in GP-treated water. The barley malt quality could be improved when GP-treated water was applied [31]. Watering peppermint with GP-treated water provided fascinating results [32]. Although such watering had no essential effect on the yield of the essential oil and plant crop yield, the composition of the essential oil dramatically changed. The menthol content in it was distinctly lower and, simultaneously, the bactericidal properties of that oil increased. Several new components of that oil could be characterized. Bioaccumulation of cations and anions in leaves, stems and roots also changed.
Several interesting applications of water treated with GP in contact with the air are presented in a review [33] newly published monograph [34]. These applications presented based on unpublished research reports deal with the plant cultivation and animal breeding.
These results prompted us to use GP for the water treatment under oxygen-free atmosphere of nitrogen. Deionized water was saturated with rigorously oxygen-free nitrogen then treated under such nitrogen for 0 (control sample), 5, 15, 30, 60 and 90 min. Physicochemical properties of resulting samples were characterized based on estimations of pH, conductivity, surface tension, differential scanning calorimetry (DSC), density and all Fourier Transformation Infrared (FTIR), and Electron Spin Resonance (ESR), Ultraviolet-Visible (UVVIS) and Raman spectra. Comparison of results of those measurements with relevant data for water treated with GP in the air gave clear evidence that both types of water were entirely different.

2. Materials and Methods

2.1. Preparation of GP-Treated Water (GPTW)

Through the deionized water a stream of nitrogen was bubbled for 15 min. Its flow rate depended on the volume of the water sample. In case of the 200 mL sample it was 10 mL/min). Nitrogen was deoxygenated by passing through an absorber filled with an alkaline solution of resorcinol. That water (200 mL) was placed in 250 mL glass bottles and free space over the liquid was additionally filled with deoxygenated nitrogen. The whole was placed in the chamber of the reactor [35] (Figure 1) and exposed to GP for 5, 15, 30, 60 and 90 min. Plasma of 38 °C was generated at 5 × 10−3 mbar, 800 V, 50 mA and 10 KHz frequency using a lamp patented by Oszczęda [36]. The produced water was stored at ambient temperature in 100 mL closed teflon containers.

2.2. Physicochemical Studies of GPTW

2.2.1. pH

The measurements for all samples (both control samples and these treated with GP for 5 to 90 min) were performed at 25 °C in triplicates with a laboratory multifunction meter CP-501 (Elmetron, Zabrze, Poland) equipped with glass electrode HYDROMET, Type ERH-11.

2.2.2. Conductivity

Estimations were performed at 25 °C with an ELMETRON CPC-505 instrument (Zabrze, Poland) equipped in an ELMETRON EC-60 sensor. The estimations were taken in triplicates for both control samples and these treated with GP for 5 to 90 min.

2.2.3. Surface Tension

The surface tension was measured with the du Nouy’a ring technique using an STA-1 tensiometer (Sinterface, Berlin, Germany) equipped in a ring of the 9.55 radius. The normal speed of the ring was applied. The measurements were performed at 24 ± 0.5 °C for 1 g/L samples of 0.997 g/L density. The experiments were run in 7 replicates.

2.2.4. Differential Scanning Calorimetry (DSC)

Differential scanning calorimeter DSC 204F1 Phoenix (Netzsch, Germany) was used. Multipoint calibration (Hg, In, Sn, Bi, Zn, CsCl) was involved. Analyzed samples (12 mg) were hermetically sealed in alumina capsules. The capsules were then punctured and cooled down to −40 °C with the rate of 10 °C/min followed with heating to 140 °C with the same rate. Characteristic temperatures and enthalpy of transitions (Tonset, Tmid, Tend and H) were determined with Proteus Analysis (Netzsch, Germany) software. Experiments were duplicated.

2.2.5. Water Density

Water sample (12 L) was placed in NETZSCH 6.239.2-64.5.00 DSC crucibles and their weight determined with precision of 10−6 g at 22 °C using a Mettler-Toledo (Greifensee, Switzerland) XPR56 balance. Density (d) was calculated from Equation d = m/V where m and V are weight and volume of the sample, respectively.

2.2.6. FTIR-ATR (Fourier Transformation Infrared—Attenuated Total Reflectance) Spectra

The FTIR-ATR spectra of the film were recorded following the method formerly described [23]. Thus, the measurements were performed in the range of 4000–700 cm−1 at resolution of 4 cm−1 using a Mattson 3000 FT-IR (Madison, Wisconsin, USA) spectrophotometer. That instrument was equipped with a 30SPEC 30° reflectance adapter fitted with the MIRacle ATR accessory from PIKE Technologies Inc., Madison, Wisconsin, USA.

2.2.7. ESR (Electron Spin Resonance) Spectra

The spectra were recorded at room temperature employing an instrument constructed at Wroclaw Technical University. The range of the X-band (v = 9.5 GHz, λ = 3.2 cm) was employed at the 20–25 dB attenuation and 2048 s swiping time. An EPR controller software designed for taking the EPR spectra was applied. For samples saturated with nitrogen g ≈ 2.16.

2.2.8. UV/VIS (Ultraviolet/Visible) Absorption Spectra

The spectra were recorded with a Thermo Scientific Evolution 220 (Thermo Fischer Scientific, Waltham, MA, USA) spectrophotometer in the wavelength range of 190–1100 nm in a quartz cell of 10 mm path length as formerly described in our recent paper [24]. The instrument was set on automatic measuring mode at medium scan speed and 1.0 nm slit width.

2.2.9. Raman Spectra

The spectra were taken with a Perkin-Elmer MPF44A Fluorescence Spectrophotometer equipped with a xenon lamp (excitation at 360 nm) and 4 mL quartz cell following the method described in [23]. The spectra were recorded for:
-
Control distilled water stored in contact with the air,
-
Control distilled water saturated with deoxygenated nitrogen
-
Distilled water saturated with deoxygenated nitrogen exposed to GP for 5, 15, 30, 60 and 90 min.

3. Results and Discussion

Performed studies delivered clear evidence for deep changes evoked by GP in the water macrostructure. The plasma used in this study was generated by a lamp with the current of 10 kHz frequency. Nevertheless, changes in the GPTW macrostructure pointed to the intervention from the waves of GHz and possibly MHz frequency. Likely, the initial frequency was multiplied accordingly as a result of so-called electromagnetic interference [37].
In the UV-absorption spectra (Figure 2) of control water containing dissolved air a shoulder of a main intensive band at 195 nm could be distinguished at approximately 230 nm. It resulted from 1A11B1 transition [3]. Its intensity was 0.225 a.u. That shoulder was followed by a weak (0.020 a.u.) maximum at 739 nm common in such spectrum of water [38]. Saturation of the water with nitrogen resulted in considerable decrease in absorbance of the shoulder to 0.151 a.u. leaving the intensity of the maximum at 739 nm intact. The spectrum represented solely the spectrum of water as the bands of molecular nitrogen could be observed in the region of 80–100 nm [39]. Thus, the decrease in the intensity of the shoulder could be related to decreased in the number of water molecules with lone electron pairs not engaged in the hydrogen bonding, that is, those providing the n → π* transitions.
According to the Roentgen hypothesis, in liquid water ice-like structures involving intermolecular hydrogen bonds coexisted with isolated H2O monomers [40]. One should keep in mind that control water, W, used in our studies contained dissolved oxygen as well as CO2, as evidenced by pH of that water (Table 1). That water had pH 5.95. Both these solutes produced a certain disorder in the macrostructure of the water. Saturating that water with nitrogen brought pH of that water to 6.68 showing that some residual CO2 could still remain in the solution. However, first of all, the number of molecules producing disorder of the macrostructure was essentially reduced as at 20 °C water dissolves 0.0425 g/kg oxygen and only 0.0185 g/kg nitrogen [41].
WN5 and WN30 water seemed to have a particular macrostructures, as evidenced by their mass, density, conductivity and surface tension (Table 1). Both samples exhibited the highest mass and density, the lowest conductivity and the highest surface tension among all prepared GP-treated water samples.
The absorbance of the shoulder at 230 nm in the spectrum of the water saturated with nitrogen, WN0, increased on treating with GP for 5 to 15 min. Thus, a disorder of the macrostructure of that water increased. Prolonged GP treatment ordered the macrostructure as it could be deduced from reduction of the absorbance of that shoulder below that in the spectrum of WN0. The 5 min GP treatment of WN0 most efficiently increased the absorbance of the shoulder but extending such treatment to 15 min reduced its intensity to that in the spectrum of non-treated water. In consequence, both spectra were like one another. The GP treatment for 30 min produced some essential change of the spectrum. The absorbance of that spectrum was initially quite low but at approximately 360 nm a jump of the spectral line was observed and, as a consequence, the intensity of the spectral line became much higher than the intensity of the remaining spectra (Figure 2). The spectra of the water GP-treated for 60 and 90 min were identical and their absorbance was the lowest among all measured spectra (Figure 2). Thus, treating WN0 with GP for 30–90 min organized its macrostructure.
FTIR spectra (Figure 3) of water in the range of 4000–1250 cm−1 consisted of two OH bands (stretching modes of the hydroxyl group) combined in one broad peak and OH (bending modes in the hydroxyl group) bands. The band situated at 3243 cm−1 is, in fact, composed of two bands reflecting asymmetric (longer wavelength) and symmetric (shorter wavelength) vibrations in the water molecule [3]. They could be recognized after the Gaussian distribution of that band. One might see that positions of all three bands were insensitive to the treatment with plasma, and the intensity of those bands subtly depended on it (see Table 2).
Saturation of the water containing dissolved air with oxygen free nitrogen increased the deal of asymmetric stretching modes of the water. It was manifested by the changes of the A/B intensity ratio. Independently of the applied GP treatment time the deal of the water molecules with asymmetrically stretched O-H bonds declined although that decline was irregular against the GP treatment time. Prolonged treatment recovered, to a certain extent, asymmetrically vibrating molecules. The presence of nitrogen resulted in some, irregular against the treatment time, increase in the intensity of the B and C bands. Such behavior differed from that of the water containing dissolved air. The latter water contained the highest number of asymmetrically vibrating molecules after the 5 min GP treatment [24].
Raman spectra taken with an instrument equipped in a xenon lamp offered the most convincing evidence for the changes of the macrostructure of water induced by the treating water with GP (Figure 4). The spectrum of control, deionized water maintained in the air, W, consisted of fairly intensive, clearly complex band centered at 365 nm followed by a shoulder and another, less intensive band at 372 nm. That band had at least two shoulders on its long wavelength side. Saturation of deionized water with oxygen-free nitrogen, WN0, essentially changed the spectral pattern. The weaker non-symmetric band at 370 nm was preceded by at least two shoulders and followed by a fairly intensive band at 377 nm. That band exhibited a weak shoulder on its long wavelength side. The treating the latter water with GP for 5 min, WN5, drastically changed the spectral pattern. A very strong complex band with shoulders on its both sides developed at 373 nm. In the region of 360–379 nm, the spectrum of the water treated with GP for 15 min, WN15, was identical with that of water treated with GP for 5 min but additional weak band appeared at 382 nm. The character of the spectrum of water treated under nitrogen for 30 min, WN30, resembled that taken for the water treated for 5 min. There was a first complex weaker band at 368 nm followed by more intensive band at 376 nm. The spectra of water treated under nitrogen for 60 (WN60) and 90 (WN90) min were considerably less intensive. They presented one complex broad band each with several shoulders. The spectrum of WN60 was more intensive than the spectrum of WN90. The maxima were centered at 375 and 371 nm, respectively.
Observed spectral changes were irregular against the GP treatment time suggesting building, for instance, aqueous clathrates of excited molecular nitrogen of varying excited states. The clathrates were formed of varying number of the guest molecules in aqueous cages built of different number of the water molecules. Such GP treatment time dependent irregularities were observed also in case of water GP-treated in the air [24].
Differential Scanning Calorimetry measurements delivered further information of the water macrostructure. The measurements were performed in the three-step regime, that is (i) freezing from room temperature to −40 °C, (ii) melting and (iii) heating to +140 °C. A typical graph is presented in Figure 5. The results are given in Table 3.
Replacement of oxygen and carbon dioxide dissolved in control water, W, with nitrogen, WN0, had little effect upon temperature of phase transitions; however, their enthalpy considerably changed. Results of the GP treatment of water saturated with nitrogen depended upon the treatment time in an irregular manner, particularly in case of freezing. Except for WN30 and WN60, T1onset, T1mid and T1end parameters increased by approximately 1 °C in respect to these for WN0. Generally, the treatment with GP produced a small decrease in the temperature parameters for melting and freezing but data for WN5 and WN30 spoiled that relation. Areas of the phase transitions declined irregularly against the treatment time.
Entropy calculated from Equation (1) (see Table 4)
ΔS = ΔH/T
declined by the treatment in the manner correlated with specific heat, Cp.
Thus, the treatment with GP changed the equilibrium between tetrahedral clathrates and ordered bulk structures. Nitrogen favored ordering of the macrostructure in respect to that in control water stored in the air probably, first of all, because of decreased content of disordering macrostructure solutes.
ESR spectra of water stored in the air exhibited a signal common for the presence of unpaired spins. They were ascribed to the triplet state of oxygen dissolved in that water. The signal ceased after the treatment of the water with GP and that fact was interpreted as the result of taking the excited singlet state [24]. In contrast to this, the ESR spectrum of the water saturated with nitrogen prior to its treatment with GP (W) did not exhibit any signal. After the treatment with GP, the ESR spectra of that water revealed a signals pattern that depended on the GP treatment time.
Figure 6 presents ESR spectra of deionized water saturated with nitrogen after treating with GP for 5 to 90 min. The time dependent pattern of the signals reflects a known complexity of the excitation of the nitrogen molecule [42,43]. This problem will be addressed in a separate paper.
These spectra demonstrated that depending on the treatment time differently built aqueous clathrates were generated with different excited state nitrogen molecules inside what was also documented in the corresponding Raman spectra (Figure 3).
In our former papers, following paper by Ramya and Venkanathan [44], formation of aqueous clathrates with singlet oxygen [24] as the guest molecules was postulated. It was suggested that molecular orbitals of those guests promoted the formation of the clathrates themselves and controlled their composition as well as their structure. Entropy values of the water treated with GP for varying time (Table 4), thus, containing various forms of excited nitrogen molecules, declined in the following order:
WN5 > WN15 > WN90 > WN60 > WN30
That order suggested the stimulation of the formation of the clathrates and their stability dependent on the excited state of the nitrogen molecule. That order roughly correlated with the order of declining absorbance of the shoulder at 230 nm in the UV absorption spectra of those waters (Figure 1), that is, with declining number of non-engaged lone electron pairs. It was equivalent to increasing ordering of the water macrostructure.

4. Conclusions

Already elimination of dissolved oxygen and carbon dioxide from deionized water by blowing with the stream of nitrogen resulted in a higher ordering of the water macrostructure.
The subsequent treatment of the water with low-temperature glow plasma of low frequency (GP) produced aqueous clathrates with nitrogen guest molecules in various exited states depending on the treatment time. Based on the entropy criterion, the macrostructure formed on 30 and 5 min GP treatment is the most and least organized, respectively. The entropy of particular macrostructures was not linear against the GP treatment time. Independently of the applied GP treatment time the deal of the water molecules with asymmetrically stretched O-H bonds declined and the decline was irregular against the treatment time. In terms of such selected physicochemical properties as mass, density, pH, conductivity and surface tension saturated with nitrogen water treated with GP for 5 and 30 min distinctly differ from the samples treated for 15, 60 and 90 min.

Author Contributions

J.C. run Raman spectra, K.C. run pH, conductivity measurements, W.C. run ESR spectra, K.K. run UV-VIS and Infrared Spectra, H.K. run Raman spectra, D.K. Thermogravimetry measurements, Z.O. equipped a research team in nanowater, P.T. invented the project, coordinated study and designed the text of this report, M.W. run surface tension and water density. All authors jointly participated in interpretation of all data and in writing report. All authors have read and agreed to the published version of the manuscript.

Funding

This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.

Acknowledgments

Authors feel very much indebted to Jacek Soroka, DSc. of West-Pomeranian University of Technology in Szczecin (Poland) for his very substantial remarks and discussion of the subject.

Conflicts of Interest

No conflict of interest is known to the authors.

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Figure 1. Scheme of the glow plasma (GP) generator and the mode of the treating water with it [35].
Figure 1. Scheme of the glow plasma (GP) generator and the mode of the treating water with it [35].
Water 12 01314 g001
Figure 2. Ultraviolet (UV) absorption spectra of controlled, deionized water maintained in the air (W) and controlled deionized water washed with nitrogen (WN0), and that latter water after the GP treatment for 5 to 90 min (WN5–WN90), respectively.
Figure 2. Ultraviolet (UV) absorption spectra of controlled, deionized water maintained in the air (W) and controlled deionized water washed with nitrogen (WN0), and that latter water after the GP treatment for 5 to 90 min (WN5–WN90), respectively.
Water 12 01314 g002
Figure 3. Fourier Transformation Infrared (FTIR) spectra of deionized water stored in contact with the air (W) and saturated with nitrogen prior (WN0) and after treating with GP for 5 to 90 min (WN5-WN90), respectively.
Figure 3. Fourier Transformation Infrared (FTIR) spectra of deionized water stored in contact with the air (W) and saturated with nitrogen prior (WN0) and after treating with GP for 5 to 90 min (WN5-WN90), respectively.
Water 12 01314 g003
Figure 4. Raman spectra of deionized water stored in contact with the air (W) and saturated with nitrogen prior (WN0) and after treating with GP for 5 to 90 min (WN5-WN90), respectively.
Figure 4. Raman spectra of deionized water stored in contact with the air (W) and saturated with nitrogen prior (WN0) and after treating with GP for 5 to 90 min (WN5-WN90), respectively.
Water 12 01314 g004
Figure 5. The typical course of the Differential Scanning Calorimetry (DSC) experiment shown for deionized water stored in the air.
Figure 5. The typical course of the Differential Scanning Calorimetry (DSC) experiment shown for deionized water stored in the air.
Water 12 01314 g005
Figure 6. Electron Spin Resonance (ESR) spectra of deionized water saturated with nitrogen treated with GP for 5 (a), 15 (b), 30 (c), 60 (d) and 90 (e) min.
Figure 6. Electron Spin Resonance (ESR) spectra of deionized water saturated with nitrogen treated with GP for 5 (a), 15 (b), 30 (c), 60 (d) and 90 (e) min.
Water 12 01314 g006aWater 12 01314 g006bWater 12 01314 g006c
Table 1. Selected physicochemical properties of control waters and water treated with GP under nitrogen.
Table 1. Selected physicochemical properties of control waters and water treated with GP under nitrogen.
Water aMass
(mg)
Density
(g/cm3) b
pHConductivity
(µS/cm)
Surface Tension
(mN/m)
W11.95 ± 0.150.9958335.953.103 ± 0.00864.99 ± 0.30
WN011.80 ± 0.200.9833336.682.353 ± 0.00768.28 ± 0.39
WN512.95 ± 0.151.0791676.722.220 ± 0.01069.22 ± 0.32
WN1511.90 ± 0.300.9916676.682.647 ± 0.00761.91 ± 0.22
WN3012.15 ± 0.051.0125006.572.343 ± 0.00767.46 ± 0.25
WN6011.30 ± 0.100.9500006.622.483 ± 0.00659.91 ± 0.61
WN9012.00 ± 0.250.9791676.592.430 ± 0.01061.73 ± 0.18
a W—deionized water stored in contact with the air, WN0—deionized water saturated with nitrogen, prior to treatment with GP, WN5-WN90 deionized water treated with GP for 5 to 90 min, respectively. b The precision of estimation did not exceed ±0.000007 g/cm3.
Table 2. Intensity of the OH stretching (bands A and B a) and bending (band C) modes in the FTIR spectra of water taken in the region of 4000–1500 cm−1.
Table 2. Intensity of the OH stretching (bands A and B a) and bending (band C) modes in the FTIR spectra of water taken in the region of 4000–1500 cm−1.
Sample bBand IntensityIntensity Ratio
A (3494 cm−1)B (3265 cm−1)C (1633 cm−1)A/BA/CB/C
W0.06420.32660.16330.1970.3932.000
WN00.08100.34030.17320.2380.4681.965
WN50.07110.33050.16930.2150.4201.952
WN150.07210.33230.16930.2170.4261.963
WN300.06810.32940.16930.2070.4021.946
WN600.07300.33150.17030.2200.4291.947
WN900.07800.33330.17030.2340.4581.957
a Bands A and B resulted from the Gaussian distribution of the main, broad band at 3251.90 cm1. b See Table 1 for notation.
Table 3. Results of the DSC measurements for water treated under nitrogen a.
Table 3. Results of the DSC measurements for water treated under nitrogen a.
Sample bFreezingMeltingEvaporating
T1onsetT1midT1endArea1T2onsetT2midT2endArea2T3onsetT3midT3endArea3
W−20.6−21.5−25.4−281.10.111.016.8−355.9100.9125.0128.8−2075.5
WN0−20.6−21.4−25.0−284.20.110.916.1−361.2101.0124.2128.0−2149.5
WN5−19.4−20.3−24.1−297.00.211.016.2−373.9101.1124.9128.9−2174.0
WN15−18.4−19.1−23.9−303.40.210.215.7−379.0101.1123.9127.6−2207.0
WN30−20.7−21.3−24.8−294.00.110.516.1−374.6100.7124.0127.8−2194.0
WN60−20.7−21.4−24.5−304.80.110.115.0−385.2101.1123.2127.0−2271.0
WN90−19.2−19.9−23.4−303.30.110.515.3−379.8100.9123.3127.0−2232.5
a Temperature is given in °C and areas in J/g. b See Table 1 for notation.
Table 4. Thermodynamic data for treated with GP deionized water saturated with nitrogen.
Table 4. Thermodynamic data for treated with GP deionized water saturated with nitrogen.
Sample aCpΔHΔS
J/gKJ/molKJ/gJ/molJ/g KJ/molK
W0.3630.026−2075.5−115.3063.943620.219090
WN011.5230.823−2149.5−119.4173.952310.219573
WN513.2540.947−2174.0−120.7783.852140.214008
WN1519.2351.374−2207.0-122.6113.521480.195638
WN3037.2352.659−2194.0−121.8893.012580.167366
WN6030.4852.177−2271.0−126.1673.254830.180824
WN9025.2371.802−2232.5−124.0283.356840.186491
a See table or notation.

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Chwastowski, J.; Ciesielska, K.; Ciesielski, W.; Khachatryan, K.; Kołoczek, H.; Kulawik, D.; Oszczęda, Z.; Tomasik, P.; Witczak, M. Structure and Physicochemical Properties of Water Treated under Nitrogen with Low-Temperature Glow Plasma. Water 2020, 12, 1314. https://doi.org/10.3390/w12051314

AMA Style

Chwastowski J, Ciesielska K, Ciesielski W, Khachatryan K, Kołoczek H, Kulawik D, Oszczęda Z, Tomasik P, Witczak M. Structure and Physicochemical Properties of Water Treated under Nitrogen with Low-Temperature Glow Plasma. Water. 2020; 12(5):1314. https://doi.org/10.3390/w12051314

Chicago/Turabian Style

Chwastowski, Jarosław, Katarzyna Ciesielska, Wojciech Ciesielski, Karen Khachatryan, Henryk Kołoczek, Damian Kulawik, Zdzisław Oszczęda, Piotr Tomasik, and Mariusz Witczak. 2020. "Structure and Physicochemical Properties of Water Treated under Nitrogen with Low-Temperature Glow Plasma" Water 12, no. 5: 1314. https://doi.org/10.3390/w12051314

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